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Structural snapshots of an Al–Cu bond-mediated transformation of terminal acetylenes

The copper(i) alumanyl derivative, [{SiN(Dipp)}Al–Cu(NHC(iPr))] (SiN(Dipp) = {CH(2)SiMe(2)NDipp}(2); Dipp = 2,6-di-isopropylphenyl; NHC(iPr) = N,N′-di-isopropyl-4,5-dimethyl-2-ylidene), reacts in a stepwise fashion with up to three equivalents of various terminal alkynes. This reactivity results in...

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Detalles Bibliográficos
Autores principales:	Liu, Han-Ying, Neale, Samuel E., Hill, Michael S., Mahon, Mary F., McMullin, Claire L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016343/ https://www.ncbi.nlm.nih.gov/pubmed/36937577 http://dx.doi.org/10.1039/d3sc00240c

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