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Redox and guest tunable spin-crossover properties in a polymeric polyoxometalate
A bifunctionalized polyoxometalate (POM), [V(6)O(19)(C(16)H(15)N(6)O)(2)](2−), which contains a redox active hexavanadate moiety covalently linked to two tridentate 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligands, has been prepared and characterized. Reaction of this hybrid molecule with Fe(ii) or Zn(...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016358/ https://www.ncbi.nlm.nih.gov/pubmed/36937587 http://dx.doi.org/10.1039/d2sc05800f |