Control of stereogenic oxygen in a helically chiral oxonium ion

The control of tetrahedral carbon stereocentres remains a focus of modern synthetic chemistry and is enabled by their configurational stability. By contrast, trisubstituted nitrogen(1), phosphorus(2) and sulfur compounds(3) undergo pyramidal inversion, a fundamental and well-recognized stereochemica...

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Detalles Bibliográficos
Autores principales: Smith, Owen, Popescu, Mihai V., Hindson, Madeleine J., Paton, Robert S., Burton, Jonathan W., Smith, Martin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10017494/
https://www.ncbi.nlm.nih.gov/pubmed/36922609
http://dx.doi.org/10.1038/s41586-023-05719-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10017494/
https://www.ncbi.nlm.nih.gov/pubmed/36922609
http://dx.doi.org/10.1038/s41586-023-05719-z

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