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Control of stereogenic oxygen in a helically chiral oxonium ion
The control of tetrahedral carbon stereocentres remains a focus of modern synthetic chemistry and is enabled by their configurational stability. By contrast, trisubstituted nitrogen(1), phosphorus(2) and sulfur compounds(3) undergo pyramidal inversion, a fundamental and well-recognized stereochemica...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10017494/ https://www.ncbi.nlm.nih.gov/pubmed/36922609 http://dx.doi.org/10.1038/s41586-023-05719-z |