Biomimetic Cationic Cyclopropanation Enables an Efficient Chemoenzymatic Synthesis of 6,8-Cycloeudesmanes

[Image: see text] Cationic cyclopropanation involves the γ-elimination at carbocations to form a new σ-C–C bond through proton loss. While exceedingly rare in bulk solution, it is recognized as one of the main biosynthetic cyclopropanation pathways. Despite the rich history of bioinspired synthetic...

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Detalles Bibliográficos
Autores principales: Grant, Phillip S., Meyrelles, Ricardo, Gajsek, Oliver, Niederacher, Gerhard, Maryasin, Boris, Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10021018/
https://www.ncbi.nlm.nih.gov/pubmed/36854118
http://dx.doi.org/10.1021/jacs.2c13116

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10021018/
https://www.ncbi.nlm.nih.gov/pubmed/36854118
http://dx.doi.org/10.1021/jacs.2c13116

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