Can Side-Chain Conformation and Glycosylation Selectivity of Hexopyranosyl Donors Be Controlled with a Dummy Ligand?

[Image: see text] The use of a phenylthio group (SPh) as a dummy ligand at the 6-position to control the side-chain conformation of a series of hexopyranosyl donors is described. The SPh group limits side-chain conformation in a configuration-specific manner, which parallels that seen in the heptopy...

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Detalles Bibliográficos
Autores principales: Upadhyaya, Kapil, Osorio-Morales, Nicolas, Crich, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10028612/
https://www.ncbi.nlm.nih.gov/pubmed/36877600
http://dx.doi.org/10.1021/acs.joc.2c02889

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10028612/
https://www.ncbi.nlm.nih.gov/pubmed/36877600
http://dx.doi.org/10.1021/acs.joc.2c02889

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