Enantioselective Allylation of Stereogenic Nitrogen Centers

[Image: see text] Most tertiary amines with a stereogenic nitrogen center undergo rapid racemization at room temperature. Consequently, the quaternization of amines under dynamic kinetic resolution seems feasible. N-Methyl tetrahydroisoquinolines are converted into configurationally stable ammonium...

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Detalles Bibliográficos
Autores principales: Zaitseva, Snizhana, Prescimone, Alessandro, Köhler, Valentin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10028698/
https://www.ncbi.nlm.nih.gov/pubmed/36881477
http://dx.doi.org/10.1021/acs.orglett.3c00195

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10028698/
https://www.ncbi.nlm.nih.gov/pubmed/36881477
http://dx.doi.org/10.1021/acs.orglett.3c00195

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