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Engineering intraporous solvent environments: effects of aqueous-organic solvent mixtures on competition between zeolite-catalyzed epoxidation and H(2)O(2) decomposition pathways
Solvent molecules alter the free energies of liquid phase species and adsorbed intermediates during catalytic reactions, thereby impacting rates and selectivities. Here, we examine these effects through the epoxidation of 1-hexene (C(6)H(12)) with hydrogen peroxide (H(2)O(2)) over hydrophilic and hy...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034100/ https://www.ncbi.nlm.nih.gov/pubmed/36970093 http://dx.doi.org/10.1039/d2sc06473a |