Aminals as powerful XAT-reagents: activation of fluorinated alkyl chlorides

Readily available 1,3,5-trimethyl-1,3,5-triazinane serves as an efficient reagent for halogen atom transfer. Under photocatalytic conditions, the triazinane generates an α-aminoalkyl radical, which can activate the C–Cl bond of fluorinated alkyl chlorides. The hydrofluoroalkylation reaction between...

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Detalles Bibliográficos
Autores principales: Kostromitin, Vladislav S., Sorokin, Artem O., Levin, Vitalij V., Dilman, Alexander D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034144/
https://www.ncbi.nlm.nih.gov/pubmed/36970090
http://dx.doi.org/10.1039/d3sc00027c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034144/
https://www.ncbi.nlm.nih.gov/pubmed/36970090
http://dx.doi.org/10.1039/d3sc00027c

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