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Aminals as powerful XAT-reagents: activation of fluorinated alkyl chlorides

Readily available 1,3,5-trimethyl-1,3,5-triazinane serves as an efficient reagent for halogen atom transfer. Under photocatalytic conditions, the triazinane generates an α-aminoalkyl radical, which can activate the C–Cl bond of fluorinated alkyl chlorides. The hydrofluoroalkylation reaction between...

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Detalles Bibliográficos
Autores principales:	Kostromitin, Vladislav S., Sorokin, Artem O., Levin, Vitalij V., Dilman, Alexander D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034144/ https://www.ncbi.nlm.nih.gov/pubmed/36970090 http://dx.doi.org/10.1039/d3sc00027c

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