Cargando…
Mechanistic study of homoleptic trisamidolanthanide-catalyzed aldehyde and ketone hydroboration. Chemically non-innocent ligand participation
Carbonyl bond hydroboration is a valuable synthetic route to functionalized alcohols but relies on sometimes unselective and sluggish reagents. While rapid and selective aldehyde and ketone hydroboration mediated by trisamidolanthanide catalysts is known, the origin of the selectivity is not well-un...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034223/ https://www.ncbi.nlm.nih.gov/pubmed/36970105 http://dx.doi.org/10.1039/d2sc06442a |