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Competitive aminal formation during the synthesis of a highly soluble, isopropyl-decorated imine porous organic cage

The synthesis of a new porous organic cage decorated with isopropyl moieties (CC21) was achieved from the reaction of triformylbenzene and an isopropyl functionalised diamine. Unlike structurally analogous porous organic cages, its synthesis proved challenging due to competitive aminal formation, ra...

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Detalles Bibliográficos
Autores principales: Kearsey, Rachel J., Tarzia, Andrew, Little, Marc A., Brand, Michael C., Clowes, Rob, Jelfs, Kim E., Cooper, Andrew I., Greenaway, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10035065/
https://www.ncbi.nlm.nih.gov/pubmed/36896582
http://dx.doi.org/10.1039/d3cc00072a