Li vs Na: Divergent Reaction Patterns between Organolithium and Organosodium Complexes and Ligand-Catalyzed Ketone/Aldehyde Methylenation

[Image: see text] Organosodium chemistry is underdeveloped compared with organolithium chemistry, and all the reported organosodium complexes exhibit similar, if not identical, reactivity patterns to their lithium counterparts. Herein, we report a rare organosodium monomeric complex, namely, [Na(CH(...

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Detalles Bibliográficos
Autores principales: Davison, Nathan, McMullin, Claire L., Zhang, Lu, Hu, Shu-Xian, Waddell, Paul G., Wills, Corinne, Dixon, Casey, Lu, Erli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10037334/
https://www.ncbi.nlm.nih.gov/pubmed/36890641
http://dx.doi.org/10.1021/jacs.3c01033

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10037334/
https://www.ncbi.nlm.nih.gov/pubmed/36890641
http://dx.doi.org/10.1021/jacs.3c01033

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