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Arene C–H borylation strategy enabled by a non-classical boron cluster-based electrophile

Introducing a tri-coordinate boron-based functional group (e.g., boronic ester) into an unactivated C–H bond in the absence of directing groups is an ongoing challenge in synthetic chemistry. Despite previous developments in transition metal-catalyzed and -free approaches, C–H borylation of sterical...

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Detalles Bibliográficos
Autores principales: Kim, Sangmin, Treacy, Joseph W., Nelson, Yessica A., Gonzalez, Jordan A. M., Gembicky, Milan, Houk, K. N., Spokoyny, Alexander M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10039867/
https://www.ncbi.nlm.nih.gov/pubmed/36966132
http://dx.doi.org/10.1038/s41467-023-37258-6