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Arene C–H borylation strategy enabled by a non-classical boron cluster-based electrophile
Introducing a tri-coordinate boron-based functional group (e.g., boronic ester) into an unactivated C–H bond in the absence of directing groups is an ongoing challenge in synthetic chemistry. Despite previous developments in transition metal-catalyzed and -free approaches, C–H borylation of sterical...
Autores principales: | Kim, Sangmin, Treacy, Joseph W., Nelson, Yessica A., Gonzalez, Jordan A. M., Gembicky, Milan, Houk, K. N., Spokoyny, Alexander M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10039867/ https://www.ncbi.nlm.nih.gov/pubmed/36966132 http://dx.doi.org/10.1038/s41467-023-37258-6 |
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