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Comparing (13)C methyl and deuterated methyl isotopic labeling for the quantification of methyl cellulose patterns using mass spectrometry

The methyl substitution along and among the polymer chains of methyl cellulose (MC) is commonly analyzed by ESI-MS after perdeuteromethylation of the free-OH groups and partial hydrolysis to cello-oligosaccharides (COS). This method requires a correct quantification of the molar ratios of the consti...

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Detalles Bibliográficos
Autores principales: Schleicher, Sarah, O’Connor, Gavin, Mischnick, Petra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10050035/
https://www.ncbi.nlm.nih.gov/pubmed/36867199
http://dx.doi.org/10.1007/s00216-023-04622-w