Evidence for a High-Valent Iron-Fluoride That Mediates Oxidative C(sp(3))-H Fluorination

[Image: see text] [Fe(II)(NCCH(3))(NTB)](OTf)(2) (NTB = tris(2-benzimidazoylmethyl)amine, OTf = trifluoromethanesulfonate) was reacted with difluoro(phenyl)-λ(3)-iodane (PhIF(2)) in the presence of a variety of saturated hydrocarbons, resulting in the oxidative fluorination of the hydrocarbons in mo...

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Detalles Bibliográficos
Autores principales: Panda, Chakadola, Anny-Nzekwue, Onyinyechukwuka, Doyle, Lorna M., Gericke, Robert, McDonald, Aidan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10052241/
https://www.ncbi.nlm.nih.gov/pubmed/37006763
http://dx.doi.org/10.1021/jacsau.3c00021

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10052241/
https://www.ncbi.nlm.nih.gov/pubmed/37006763
http://dx.doi.org/10.1021/jacsau.3c00021

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