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Exploration of Solid-State vs Solution-State Structure in Contact Ion Pair Systems: Synthesis, Characterization, and Solution-State Dynamics of Zinc Diphenyl Phosphate, [Zn{O(2)P(OPh)(2)}(2)], Donor-Base-Supported Complexes

[Image: see text] A family of zinc phosphate complexes supported by nitrogen donor-base ligands have been synthesized, and their molecular structures were identified in both the solid (X-ray crystallography) and solution state (DOSY NMR spectroscopy). [Zn{O(2)P(OPh)(2)}(2)](∞) (1), formed from the r...

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Detalles Bibliográficos
Autores principales: Straiton, Andrew J., Parish, James D., Smith, Joshua J., Lowe, John P., Johnson, Andrew L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10052378/
https://www.ncbi.nlm.nih.gov/pubmed/36916880
http://dx.doi.org/10.1021/acs.inorgchem.2c03539