Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe(iii) N-heterocyclic carbene complexes

Steady state and ultrafast spectroscopy on [Fe(III)(phtmeimb)(2)]PF(6) (phtmeimb = phenyl(tris(3-methylimidazol-2-ylidene))borate) was performed over a broad range of temperatures. The intramolecular deactivation dynamics of the luminescent doublet ligand-to-metal charge-transfer ((2)LMCT) state was...

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Detalles Bibliográficos
Autores principales: Rosemann, Nils W., Lindh, Linnea, Bolaño Losada, Iria, Kaufhold, Simon, Prakash, Om, Ilic, Aleksandra, Schwarz, Jesper, Wärnmark, Kenneth, Chábera, Pavel, Yartsev, Arkady, Persson, Petter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10056060/
https://www.ncbi.nlm.nih.gov/pubmed/37006696
http://dx.doi.org/10.1039/d2sc05357h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10056060/
https://www.ncbi.nlm.nih.gov/pubmed/37006696
http://dx.doi.org/10.1039/d2sc05357h

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