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Low-Temperature Observation of the Excited-State Decay of Ruthenium-(Mono-2,2′:6′,2″-Terpyridine) Ions with Innocent Ligands: DFT Modeling of an (3)MLCT–(3)MC Intersystem Crossing Pathway
[Image: see text] The synthesis, electrochemistry, and photophysical characterization of five 2,2′:6′,2″-terpyridine ruthenium complexes (Ru-tpy complexes) is reported. The electrochemical and photophysical behavior varied depending on the ligands, i.e., amine (NH(3)), acetonitrile (AN), and bis(pyr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061511/ https://www.ncbi.nlm.nih.gov/pubmed/37008138 http://dx.doi.org/10.1021/acsomega.3c01006 |