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Low-Temperature Observation of the Excited-State Decay of Ruthenium-(Mono-2,2′:6′,2″-Terpyridine) Ions with Innocent Ligands: DFT Modeling of an (3)MLCT–(3)MC Intersystem Crossing Pathway

[Image: see text] The synthesis, electrochemistry, and photophysical characterization of five 2,2′:6′,2″-terpyridine ruthenium complexes (Ru-tpy complexes) is reported. The electrochemical and photophysical behavior varied depending on the ligands, i.e., amine (NH(3)), acetonitrile (AN), and bis(pyr...

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Detalles Bibliográficos
Autores principales:	Yin, Chi-Wei, Tsai, Ming-Kang, Chen, Yuan Jang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061511/ https://www.ncbi.nlm.nih.gov/pubmed/37008138 http://dx.doi.org/10.1021/acsomega.3c01006

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