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Accessing Heteroannular Benzoxazole and Benzimidazole Scaffolds via Carbodiimides Using Azide–Isocyanide Cross-Coupling as Catalyzed by Mesoionic Singlet Palladium Carbene Complexes Derived from a Phenothiazine Moiety

[Image: see text] The coupling of aryl and aliphatic azides with isocyanides yielding carbodiimides (8–17) were efficiently catalyzed by well-defined structurally characterized trans-(MIC)PdI(2)(L) [MIC = 1-CH(2)Ph-3-Me-4-(CH(2)N(C(6)H(4))(2)S)-1,2,3-triazol-5-ylidene, L = NC(5)H(5) (4), MesNC (5)],...

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Detalles Bibliográficos
Autores principales: Dey, Shreyata, Ghosh, Prasenjit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061513/
https://www.ncbi.nlm.nih.gov/pubmed/37008148
http://dx.doi.org/10.1021/acsomega.2c07875