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Accessing Heteroannular Benzoxazole and Benzimidazole Scaffolds via Carbodiimides Using Azide–Isocyanide Cross-Coupling as Catalyzed by Mesoionic Singlet Palladium Carbene Complexes Derived from a Phenothiazine Moiety
[Image: see text] The coupling of aryl and aliphatic azides with isocyanides yielding carbodiimides (8–17) were efficiently catalyzed by well-defined structurally characterized trans-(MIC)PdI(2)(L) [MIC = 1-CH(2)Ph-3-Me-4-(CH(2)N(C(6)H(4))(2)S)-1,2,3-triazol-5-ylidene, L = NC(5)H(5) (4), MesNC (5)],...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061513/ https://www.ncbi.nlm.nih.gov/pubmed/37008148 http://dx.doi.org/10.1021/acsomega.2c07875 |