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Are U–U Bonds Inside Fullerenes Really Unwilling Bonds?

[Image: see text] Previous characterizations of diactinide endohedral metallofullerenes (EMFs) Th(2)@C(80) and U(2)@C(80) have shown that although the two Th(3+) ions form a strong covalent bond within the carbon cage, the interaction between the U(3+) ions is weaker and described as an “unwilling”...

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Detalles Bibliográficos
Autores principales: Moreno-Vicente, Antonio, Roselló, Yannick, Chen, Ning, Echegoyen, Luis, Dunk, Paul W., Rodríguez-Fortea, Antonio, de Graaf, Coen, Poblet, Josep M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10064334/
https://www.ncbi.nlm.nih.gov/pubmed/36872864
http://dx.doi.org/10.1021/jacs.2c12346