Cargando…
Are U–U Bonds Inside Fullerenes Really Unwilling Bonds?
[Image: see text] Previous characterizations of diactinide endohedral metallofullerenes (EMFs) Th(2)@C(80) and U(2)@C(80) have shown that although the two Th(3+) ions form a strong covalent bond within the carbon cage, the interaction between the U(3+) ions is weaker and described as an “unwilling”...
Autores principales: | Moreno-Vicente, Antonio, Roselló, Yannick, Chen, Ning, Echegoyen, Luis, Dunk, Paul W., Rodríguez-Fortea, Antonio, de Graaf, Coen, Poblet, Josep M. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10064334/ https://www.ncbi.nlm.nih.gov/pubmed/36872864 http://dx.doi.org/10.1021/jacs.2c12346 |
Ejemplares similares
-
U(2)N@I(h)(7)-C(80): fullerene cage encapsulating an unsymmetrical U(iv)[double bond, length as m-dash]N[double bond, length as m-dash]U(v) cluster
por: Li, Xiaomeng, et al.
Publicado: (2020) -
Characterization of a strong covalent Th(3+)–Th(3+) bond inside an I(h)(7)-C(80) fullerene cage
por: Zhuang, Jiaxin, et al.
Publicado: (2021) -
Transformation of doped graphite into cluster-encapsulated fullerene cages
por: Mulet-Gas, Marc, et al.
Publicado: (2017) -
Actinide-lanthanide single electron metal-metal bond formed in mixed-valence di-metallofullerenes
por: Yan, Yingjing, et al.
Publicado: (2023) -
A charged diatomic triple-bonded U≡N species trapped in C(82) fullerene cages
por: Meng, Qingyu, et al.
Publicado: (2022)