Rupturing aromaticity by periphery overcrowding

The balance between strain relief and aromatic stabilization dictates the form and function of non-planar π-aromatics. Overcrowded systems are known to undergo geometric deformations, but the energetically favourable π-electron delocalization of their aromatic ring(s) is typically preserved. In this...

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Detalles Bibliográficos
Autores principales: Saha, Promeet K., Mallick, Abhijit, Turley, Andrew T., Bismillah, Aisha N., Danos, Andrew, Monkman, Andrew P., Avestro, Alyssa-Jennifer, Yufit, Dmitry S., McGonigal, Paul R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070187/
https://www.ncbi.nlm.nih.gov/pubmed/36879076
http://dx.doi.org/10.1038/s41557-023-01149-6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070187/
https://www.ncbi.nlm.nih.gov/pubmed/36879076
http://dx.doi.org/10.1038/s41557-023-01149-6

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