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Transition-metal-free silylboronate-mediated cross-couplings of organic fluorides with amines

C–N bond cross-couplings are fundamental in the field of organic chemistry. Herein, silylboronate-mediated selective defluorinative cross-coupling of organic fluorides with secondary amines via a transition-metal-free strategy is disclosed. The cooperation of silylboronate and potassium tert-butoxid...

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Detalles Bibliográficos
Autores principales: Zhou, Jun, Zhao, Zhengyu, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070422/
https://www.ncbi.nlm.nih.gov/pubmed/37012229
http://dx.doi.org/10.1038/s41467-023-37466-0