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Pyridine-4-thiol as halo­gen-bond (HaB) acceptor: influence of the noncovalent inter­action in its reactivity

The study of pyri­dine-4-thiol as a halo­gen-bond (HaB) acceptor has allowed the isolation of its cocrystal with the HaB donor IC(6)F(4)I, namely, 1,2,4,5-tetra­fluoro-3,6-di­iodo­benzene bis­(pyri­din-1-ium-4-ylsul­fanide), C(6)F(4)I(2)·2C(5)H(5)NS (1), where the S atom is the HaB acceptor, while t...

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Detalles Bibliográficos
Autores principales: Mosquera, Marta E. G., Dortez, Silvia, Fernández-Palacio, Francisco, Gómez-Sal, Pilar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074038/
https://www.ncbi.nlm.nih.gov/pubmed/36919972
http://dx.doi.org/10.1107/S205322962300205X