C–H bond activation via concerted metalation–deprotonation at a palladium(iii) center

Herein we report the direct observation of C–H bond activation at an isolated mononuclear Pd(iii) center. The oxidation of the Pd(ii) complex ((Me)N4)Pd(II)(neophyl)Cl (neophyl = –CH(2)C(CH(3))(2)Ph; (Me)N4 = N,N′-dimethyl-2,11-diaza[3.3](2,6)pyridinophane) using the mild oxidant ferrocenium hexaflu...

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Detalles Bibliográficos
Autores principales: Bouley, Bailey S., Tang, Fengzhi, Bae, Dae Young, Mirica, Liviu M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074423/
https://www.ncbi.nlm.nih.gov/pubmed/37035706
http://dx.doi.org/10.1039/d3sc00034f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074423/
https://www.ncbi.nlm.nih.gov/pubmed/37035706
http://dx.doi.org/10.1039/d3sc00034f

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