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Fluorocarbyne complexes via electrophilic fluorination of carbido ligands

The new fluorocarbynes [M([triple bond, length as m-dash]CF)(CO)(2)(Tp*)] (M = Mo, W; Tp* = tris(dimethylpyrazolyl)borate) arise from electrophilic fluorination of the lithiocarbynes [M([triple bond, length as m-dash]CLi)(CO)(2)(Tp*)] with FN(SO(2)Ph)(2). The reactions of [W([triple bond, length as...

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Detalles Bibliográficos
Autores principales: Manzano, Richard A., Hill, Anthony F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074445/
https://www.ncbi.nlm.nih.gov/pubmed/37035689
http://dx.doi.org/10.1039/d3sc00261f