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Fluorocarbyne complexes via electrophilic fluorination of carbido ligands
The new fluorocarbynes [M([triple bond, length as m-dash]CF)(CO)(2)(Tp*)] (M = Mo, W; Tp* = tris(dimethylpyrazolyl)borate) arise from electrophilic fluorination of the lithiocarbynes [M([triple bond, length as m-dash]CLi)(CO)(2)(Tp*)] with FN(SO(2)Ph)(2). The reactions of [W([triple bond, length as...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074445/ https://www.ncbi.nlm.nih.gov/pubmed/37035689 http://dx.doi.org/10.1039/d3sc00261f |