Cargando…
Fluorocarbyne complexes via electrophilic fluorination of carbido ligands
The new fluorocarbynes [M([triple bond, length as m-dash]CF)(CO)(2)(Tp*)] (M = Mo, W; Tp* = tris(dimethylpyrazolyl)borate) arise from electrophilic fluorination of the lithiocarbynes [M([triple bond, length as m-dash]CLi)(CO)(2)(Tp*)] with FN(SO(2)Ph)(2). The reactions of [W([triple bond, length as...
Autores principales: | Manzano, Richard A., Hill, Anthony F. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074445/ https://www.ncbi.nlm.nih.gov/pubmed/37035689 http://dx.doi.org/10.1039/d3sc00261f |
Ejemplares similares
-
Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh
por: Pell, Christopher J., et al.
Publicado: (2017) -
A quantitative reactivity scale for electrophilic fluorinating reagents
por: Rozatian, Neshat, et al.
Publicado: (2018) -
Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
por: Han, Jianlin, et al.
Publicado: (2020) -
Kinetics of Electrophilic Fluorination of Steroids and Epimerisation of Fluorosteroids
por: Rozatian, Neshat, et al.
Publicado: (2020) -
Ionic Liquid-Assisted Grinding: An Electrophilic Fluorination Benchmark
por: Zaikin, Pavel A., et al.
Publicado: (2021)