Protonation of P-Stereogenic Phosphiranes: Phospholane Formation via Ring Opening and C–H Activation

[Image: see text] Protonation of cyclopropanes and aziridines is well-studied, but reactions of phosphiranes with acids are rare and have not been reported to result in ring opening. Treatment of syn-Mes*PCH(2)CHR (Mes* = 2,4,6-(t-Bu)(3)C(6)H(2), R = Me or Ph, syn-1-2) or anti-Mes*PCH(2)CHPh (anti-2...

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Detalles Bibliográficos
Autores principales: Tipker, Ryan M., Muldoon, Jake A., Jo, Jacob, Connors, Christopher S., Varga, Balazs R., Hughes, Russell P., Glueck, David S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10077540/
https://www.ncbi.nlm.nih.gov/pubmed/37033828
http://dx.doi.org/10.1021/acsomega.3c00885

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10077540/
https://www.ncbi.nlm.nih.gov/pubmed/37033828
http://dx.doi.org/10.1021/acsomega.3c00885

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