Enantiospecific Syntheses of Congested Atropisomers through Chiral Bis(aryne) Synthetic Equivalents

The synthetic equivalents of the enantiopure binaphthyl bis(aryne) atropisomers derived from BINOL (1,1′‐bi‐2,2′‐naphtol) featuring a stereogenic axis vicinal to the two reactive triple bonds can be generated for the first time in solution in an enantiospecific manner. Using a two‐step sequence base...

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Detalles Bibliográficos
Autores principales: Dauvergne, Guillaume, Naubron, Jean‐Valère, Giorgi, Michel, Bugaut, Xavier, Rodriguez, Jean, Carissan, Yannick, Coquerel, Yoann
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10087792/
https://www.ncbi.nlm.nih.gov/pubmed/35943888
http://dx.doi.org/10.1002/chem.202202473

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10087792/
https://www.ncbi.nlm.nih.gov/pubmed/35943888
http://dx.doi.org/10.1002/chem.202202473

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