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The Influence of Deuterium Isotope Effects on Structural Rearrangements, Ensemble Equilibria, and Hydrogen Bonding in Protic Ionic Liquids

We report strong isotope effects for the protic ionic liquid triethylammonium methanesulfonate [TEA][OMs] by means of deuterium solid‐state NMR spectroscopy covering broad temperature ranges from 65 K to 313 K. Both isotopically labelled PILs differ in non‐deuterated and fully deuterated ethyl group...

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Detalles Bibliográficos
Autores principales: Khudozhitkov, Alexander E., Stange, Peter, Paschek, Dietmar, Stepanov, Alexander G., Kolokolov, Daniil I., Ludwig, Ralf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10087857/
https://www.ncbi.nlm.nih.gov/pubmed/35944124
http://dx.doi.org/10.1002/cphc.202200557