Unexpected Diastereomer Formation and Interconversions in Cyclohexane-1,2-diacetal Derivatization of a Glucuronic Acid Thioglycoside

[Image: see text] Reactions of a glucuronic acid (GlcA) β-thioglycoside with cyclohexadione show initial formation of the two anticipated all-trans decalin-type O2,O3 and O3,O4 cyclohexane-1,2-diacetals (CDAs) along with an epimer of the main O2,O3 acetal. This trans–cis isomer is then interconverte...

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Detalles Bibliográficos
Autores principales: Alharthi, Fahad Ayesh, Potter, Garrett T., Jayson, Gordon C., Whitehead, George F. S., Vitórica-Yrezábal, Iñigo J., Gardiner, John M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088025/
https://www.ncbi.nlm.nih.gov/pubmed/36972327
http://dx.doi.org/10.1021/acs.orglett.3c00255

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088025/
https://www.ncbi.nlm.nih.gov/pubmed/36972327
http://dx.doi.org/10.1021/acs.orglett.3c00255

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