Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Sulfur and Selenium: From Chalcogenophosphinidene- to Trithiophosphonate-Bridged Derivatives

[Image: see text] Reactions of [MoReCp(μ-PR*)(CO)(6)] with S(8) were strongly dependent on experimental conditions (R* = 2,4,6-C(6)H(2)(t)Bu(3)). When using 1 equiv of sulfur, complex [MoReCp(μ-η(2):κ(1)(S)-SPR*)(CO)(6)] was slowly formed at 313 K, with a thiophosphinidene ligand unexpectedly bridgi...

Descripción completa

Detalles Bibliográficos
Autores principales: Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, Patricia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091403/
https://www.ncbi.nlm.nih.gov/pubmed/36989490
http://dx.doi.org/10.1021/acs.inorgchem.3c00230

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091403/
https://www.ncbi.nlm.nih.gov/pubmed/36989490
http://dx.doi.org/10.1021/acs.inorgchem.3c00230

Ejemplares similares