Role of Multiple Vanadium Centers on Redox Buffering and Rates of Polyvanadomolybdate-Cu(II)-Catalyzed Aerobic Oxidations

[Image: see text] A recent report established that the tetrabutylammonium (TBA) salt of hexavanadopolymolybdate TBA(4)H(5)[PMo(6)V(6)O(40)] (PV(6)Mo(6)) serves as the redox buffer with Cu(II) as a co-catalyst for aerobic deodorization of thiols in acetonitrile. Here, we document the profound impact...

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Detalles Bibliográficos
Autores principales: Lu, Xinlin, Geletii, Yurii V., Cheng, Ting, Hill, Craig L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091476/
https://www.ncbi.nlm.nih.gov/pubmed/36977374
http://dx.doi.org/10.1021/acs.inorgchem.3c00469

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091476/
https://www.ncbi.nlm.nih.gov/pubmed/36977374
http://dx.doi.org/10.1021/acs.inorgchem.3c00469

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