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Role of Multiple Vanadium Centers on Redox Buffering and Rates of Polyvanadomolybdate-Cu(II)-Catalyzed Aerobic Oxidations
[Image: see text] A recent report established that the tetrabutylammonium (TBA) salt of hexavanadopolymolybdate TBA(4)H(5)[PMo(6)V(6)O(40)] (PV(6)Mo(6)) serves as the redox buffer with Cu(II) as a co-catalyst for aerobic deodorization of thiols in acetonitrile. Here, we document the profound impact...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091476/ https://www.ncbi.nlm.nih.gov/pubmed/36977374 http://dx.doi.org/10.1021/acs.inorgchem.3c00469 |