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Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex

[Image: see text] To improve Cu-based water oxidation (WO) catalysts, a proper mechanistic understanding of these systems is required. In contrast to other metals, high-oxidation-state metal–oxo species are unlikely intermediates in Cu-catalyzed WO because π donation from the oxo ligand to the Cu ce...

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Detalles Bibliográficos
Autores principales: den Boer, Daan, Konovalov, Andrey I., Siegler, Maxime A., Hetterscheid, Dennis G. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091478/
https://www.ncbi.nlm.nih.gov/pubmed/36989161
http://dx.doi.org/10.1021/acs.inorgchem.3c00477