The Mechanism of Formation of Active Fe-TAMLs Using HClO Enlightens Design for Maximizing Catalytic Activity at Environmentally Optimal, Circumneutral pH

[Image: see text] Fe-TAML/peroxide catalysis provides simple, powerful, ultradilute approaches for removing micropollutants from water. The typically rate-determining interactions of H(2)O(2) with Fe-TAMLs (rate constant k(I)) are sharply pH-sensitive with rate maxima in the pH 9–10 window. Fe-TAML...

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Detalles Bibliográficos
Autores principales: Pal, Parameswar, Schafer, Marcus C., Hendrich, Michael P., Ryabov, Alexander D., Collins, Terrence J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091481/
https://www.ncbi.nlm.nih.gov/pubmed/36967523
http://dx.doi.org/10.1021/acs.inorgchem.3c00104

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091481/
https://www.ncbi.nlm.nih.gov/pubmed/36967523
http://dx.doi.org/10.1021/acs.inorgchem.3c00104

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