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The Mechanism of Formation of Active Fe-TAMLs Using HClO Enlightens Design for Maximizing Catalytic Activity at Environmentally Optimal, Circumneutral pH
[Image: see text] Fe-TAML/peroxide catalysis provides simple, powerful, ultradilute approaches for removing micropollutants from water. The typically rate-determining interactions of H(2)O(2) with Fe-TAMLs (rate constant k(I)) are sharply pH-sensitive with rate maxima in the pH 9–10 window. Fe-TAML...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091481/ https://www.ncbi.nlm.nih.gov/pubmed/36967523 http://dx.doi.org/10.1021/acs.inorgchem.3c00104 |