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Understanding the Surprising Oxidation Chemistry of Au−OH Complexes

Au is known to be fairly redox inactive (in catalysis) and bind oxygen adducts only quite weakly. It is thus rather surprising that stable Au−OH complexes can be synthesized and used as oxidants for both one‐ and two‐electron oxidations. A charged Au(III)−OH complex has been shown to cleave C−H and...

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Detalles Bibliográficos
Autores principales: Engbers, Silène, Klein, Johannes E. M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091708/
https://www.ncbi.nlm.nih.gov/pubmed/36104296
http://dx.doi.org/10.1002/cphc.202200475