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Understanding the Surprising Oxidation Chemistry of Au−OH Complexes
Au is known to be fairly redox inactive (in catalysis) and bind oxygen adducts only quite weakly. It is thus rather surprising that stable Au−OH complexes can be synthesized and used as oxidants for both one‐ and two‐electron oxidations. A charged Au(III)−OH complex has been shown to cleave C−H and...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091708/ https://www.ncbi.nlm.nih.gov/pubmed/36104296 http://dx.doi.org/10.1002/cphc.202200475 |