Cargando…

Influence of Achiral Phosphine Ligands on a Synergistic Organo‐ and Palladium‐Catalyzed Asymmetric Allylic Alkylation

An unusual diastereodivergent stereoselective allylation reaction is presented. It consists of a palladium‐catalyzed allylation reaction of an organocatalytically generated amino isobenzofulvene, where the diastereoselectivity is controlled by the electronic properties of a monodentate, achiral liga...

Descripción completa

Detalles Bibliográficos
Autores principales: McLeod, David, Inunnguaq Jessen, Nicolaj, Nguyen, Thanh V. Q., Espe, Marcus, Erickson, Jeremy David, Anker Jørgensen, Karl, Yang, Limin, Houk, K. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10091967/
https://www.ncbi.nlm.nih.gov/pubmed/36129762
http://dx.doi.org/10.1002/chem.202202951