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Bromine Pentafluoride BrF(5), the Formation of [BrF(6)](−) Salts, and the Stereochemical (In)activity of the Bromine Lone Pairs
BrF(5) can be prepared by treating BrF(3) with fluorine under UV light in the region of 300 to 400 nm at room temperature. It was analyzed by UV‐Vis, NMR, IR and Raman spectroscopy. Its crystal structure was redetermined by X‐ray diffraction, and its space group was corrected to Pnma. Quantum‐chemic...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092034/ https://www.ncbi.nlm.nih.gov/pubmed/36106827 http://dx.doi.org/10.1002/chem.202202466 |