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A Quantum‐chemical Analysis on the Lewis Acidity of Diarylhalonium Ions

Cyclic diaryliodonium compounds like iodolium derivatives have increasingly found use as noncovalent Lewis acids in the last years. They are more stable toward nucleophilic substitution than acyclic systems and are markedly more Lewis acidic. Herein, this higher Lewis acidity is analyzed and explain...

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Detalles Bibliográficos
Autores principales: Robidas, Raphaël, Reinhard, Dominik L., Huber, Stefan M., Legault, Claude Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092059/
https://www.ncbi.nlm.nih.gov/pubmed/36043491
http://dx.doi.org/10.1002/cphc.202200634