Theoretical and Experimental Investigation of Functionalized Cyanopyridines Yield an Anolyte with an Extremely Low Reduction Potential for Nonaqueous Redox Flow Batteries

Cyanopyridines and cyanophenylpyridines were investigated as anolytes for nonaqueous redox flow batteries (RFBs). The three isomers of cyanopyridine are reduced at potentials of −2.2 V or lower vs. ferrocene(+/0) (Fc(+/0)), but the 3‐CNPy⋅(−) radical anion forms a sigma‐dimer that is re‐oxidized at...

Descripción completa

Detalles Bibliográficos
Autores principales: Vaid, Thomas P., Cook, Monique E., Scott, Jessica D., Borjesson Carazo, Marino, Ruchti, Jonathan, Minteer, Shelley D., Sigman, Matthew S., McNeil, Anne J., Sanford, Melanie S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092174/
https://www.ncbi.nlm.nih.gov/pubmed/36164261
http://dx.doi.org/10.1002/chem.202202147

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092174/
https://www.ncbi.nlm.nih.gov/pubmed/36164261
http://dx.doi.org/10.1002/chem.202202147

Ejemplares similares