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One‐step Oxidative Monofluorination of Electron‐Deficient Sulfoxides to Access Highly Lewis Acidic Sulfur(VI) Cations

The strongly oxidizing, powerful electrophilic fluorination reagent [FXe][OTf] is shown to effect direct oxidative monofluorination of sulfoxides. This one‐step, chloride promoter‐free methodology provides access to so far inaccessible, yet highly desirable strongly Lewis acidic fluorosulfoxonium ca...

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Detalles Bibliográficos
Autores principales: Berreur, Jordan, Diez‐Varga, Alberto, Manel, Augustin, Leroux, Frédéric R., Panossian, Armen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092253/
https://www.ncbi.nlm.nih.gov/pubmed/36047996
http://dx.doi.org/10.1002/chem.202202564