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One‐step Oxidative Monofluorination of Electron‐Deficient Sulfoxides to Access Highly Lewis Acidic Sulfur(VI) Cations
The strongly oxidizing, powerful electrophilic fluorination reagent [FXe][OTf] is shown to effect direct oxidative monofluorination of sulfoxides. This one‐step, chloride promoter‐free methodology provides access to so far inaccessible, yet highly desirable strongly Lewis acidic fluorosulfoxonium ca...
Autores principales: | Berreur, Jordan, Diez‐Varga, Alberto, Manel, Augustin, Leroux, Frédéric R., Panossian, Armen |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092253/ https://www.ncbi.nlm.nih.gov/pubmed/36047996 http://dx.doi.org/10.1002/chem.202202564 |
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