E‐selective Semi‐hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex

The synthesis, characterization and catalytic activity of a new class of diruthenium hydrido carbonyl complexes bound to the ( t Bu ) PNNP expanded pincer ligand is described. Reacting ( t Bu ) PNNP with two equiv of RuHCl(PPh(3))(3)(CO) at 140 °C produces an insoluble air‐stable complex, which was...

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Detalles Bibliográficos
Autores principales: van Beek, Cody B., Killian, Lars, Lutz, Martin, Weingarth, Markus, Asundi, Arun S., Sarangi, Ritimukta, Klein Gebbink, Robertus J. M., Broere, Daniël L. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092327/
https://www.ncbi.nlm.nih.gov/pubmed/35979748
http://dx.doi.org/10.1002/chem.202202527

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092327/
https://www.ncbi.nlm.nih.gov/pubmed/35979748
http://dx.doi.org/10.1002/chem.202202527

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